{rfName}
Hy

Indexed in

License and use

Altmetrics

Analysis of institutional authors

Nabgan WCorresponding AuthorDjellabi RAuthor

Share

February 20, 2023
Publications
>
Article
Hybrid Gold

Hydrogen and valuable liquid fuel production from the in-situ pyrolysis-catalytic steam reforming reactions of cellulose bio-polymer wastes dissolved in phenol over trimetallic Ni-La-Pd/TiCa nanocatalysts

Publicated to:Journal Of Environmental Chemical Engineering. 11 (2): 109311- - 2023-04-01 11(2), DOI: 10.1016/j.jece.2023.109311

Authors: Nabgan, Walid; Abdullah, T A Tuan; Ikram, M; Owgi, A H K; Hatta, A H; Alhassan, M; Aziz, F F A; Jalil, A A; Van Tran, Thuan; Djellabi, Ridha

Affiliations

Government College University Lahore - Author
Govt Coll Univ Lahore, Dept Phys, Solar Cell Applicat Res Lab, Punjab 54000, Pakistan - Author
Nguyen Tat Thanh Univ, Inst Appl Technol & Sustainable Dev, 300 A Nguyen Tat Thanh,Dist 4, Ho Chi Minh City 755414, Vietnam - Author
Nguyen Tat Thanh University , Universiti Teknologi Malaysia - Author
Univ Rovira & Virgili, Dept Engn Quim, Av Paisos Catalans 26, Tarragona 43007, Spain - Author
Univ Teknol Malaysia, Fac Chem & Energy Engn, Skudai 81310, Johor, Malaysia - Author
Universitat Rovira i Virgili - Author
Universiti Teknologi Malaysia - Author
See more

Abstract

Hydrogen and liquid fuel production from biopolymer waste, such as cellulose dissolved in phenol, was investigated using in-situ pyrolysis-catalytic steam reforming conditions. Developing a sustainable method for the thermal cracking of such biopolymers still faces difficulties due to the catalyst stability primarily impacted by coke deposition. The key to the proposed method is improving a highly active and stable catalytic reforming process in which trimetallic Ni-La-Pd supported on TiCa acts as a primary reforming catalyst. Catalysts were prepared by hydrothermal, and impregnation techniques, and the physicochemical characteristics of the fresh and spent materials were examined. The results showed that the NLP/TiCa catalysts performed effectively due to their comparatively high surface area, strong basicity, evenly distributed Pd particles, and appropriate redox and desorption characteristics. The addition of Pd retards the reducibility of the NL/TiCa; therefore, a Pd∗La, La∗Ni, La∗Ti, and Ca∗Ti interaction exist. Almost complete conversion of phenol (98.7%) and maximum H2 yield (99.6%) were achieved at 800 °C for the NLP/TiCa. These findings give an insight into industrial-scale development. They have significant potential for enhancing the generation of hydrogen and liquid products from phenol and cellulose waste, such as propanol, ethanol, toluene, etc.

Keywords

bio-polymerdesorptionethanolftirhydrogenmethaneni-la-pdnickelpolyethylenestabilitystructure dependencesurfacetrimetallicBimetallic catalystsBio-polymerCelluloseHydrogenNi-la-pdTrimetallic

Quality index

Bibliometric impact. Analysis of the contribution and dissemination channel

The work has been published in the journal Journal Of Environmental Chemical Engineering due to its progression and the good impact it has achieved in recent years, according to the agency WoS (JCR), it has become a reference in its field. In the year of publication of the work, 2023, it was in position 18/170, thus managing to position itself as a Q1 (Primer Cuartil), in the category Engineering, Chemical. Notably, the journal is positioned above the 90th percentile.

From a relative perspective, and based on the normalized impact indicator calculated from World Citations provided by WoS (ESI, Clarivate), it yields a value for the citation normalization relative to the expected citation rate of: 1.38. This indicates that, compared to works in the same discipline and in the same year of publication, it ranks as a work cited above average. (source consulted: ESI Nov 14, 2024)

This information is reinforced by other indicators of the same type, which, although dynamic over time and dependent on the set of average global citations at the time of their calculation, consistently position the work at some point among the top 50% most cited in its field:

  • Weighted Average of Normalized Impact by the Scopus agency: 2.17 (source consulted: FECYT Feb 2024)
  • Field Citation Ratio (FCR) from Dimensions: 3.24 (source consulted: Dimensions Jul 2025)

Specifically, and according to different indexing agencies, this work has accumulated citations as of 2025-07-21, the following number of citations:

  • WoS: 12
  • Scopus: 15

Impact and social visibility

From the perspective of influence or social adoption, and based on metrics associated with mentions and interactions provided by agencies specializing in calculating the so-called "Alternative or Social Metrics," we can highlight as of 2025-07-21:

  • The use of this contribution in bookmarks, code forks, additions to favorite lists for recurrent reading, as well as general views, indicates that someone is using the publication as a basis for their current work. This may be a notable indicator of future more formal and academic citations. This claim is supported by the result of the "Capture" indicator, which yields a total of: 33 (PlumX).

With a more dissemination-oriented intent and targeting more general audiences, we can observe other more global scores such as:

    It is essential to present evidence supporting full alignment with institutional principles and guidelines on Open Science and the Conservation and Dissemination of Intellectual Heritage. A clear example of this is:

    • The work has been submitted to a journal whose editorial policy allows open Open Access publication.
    • Assignment of a Handle/URN as an identifier within the deposit in the Institutional Repository: http://hdl.handle.net/20.500.11797/imarina9291932

    Leadership analysis of institutional authors

    This work has been carried out with international collaboration, specifically with researchers from: Malaysia; Pakistan; Vietnam.

    There is a significant leadership presence as some of the institution’s authors appear as the first or last signer, detailed as follows: First Author (Nabgan, Walid) and Last Author (Djellabi, Ridha).

    the author responsible for correspondence tasks has been Nabgan, Walid.